Efficient amination of sulfides with a ketomalonate-derived oxaziridine: application to [2,3]-sigmatropic rearrangements of allylic sulfimides |
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| Authors: | Armstrong Alan Cooke Richard S |
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| Affiliation: | Department of Chemistry, Imperial College, London, UK SW7 2AY. A.Armstrong@ic.ac.uk |
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| Abstract: | A novel N-Boc-oxaziridine is reported, derived from diethyl ketomalonate, which effects efficient amination of sulfides to sulfimides. The reagent is applied to the [2,3]-sigmatropic rearrangement of allylic sulfimides. |
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