Palladium dimethylsilanedithiolato complex: a precursor for Ti-Pd and Ti-Pd2 heterometallic complexes |
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| Authors: | Komuro Takashi Matsuo Tsukasa Kawaguchi Hiroyuki Tatsumi Kazuyuki |
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| Institution: | Research Center for Materials Science, Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan. |
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| Abstract: | The silanedithiolato complex Pd(S2SiMe2)(PEt3)2 1 reacted with (C5H5)TiCl3 and TiCl4(thf)2 to produce the heterometallic clusters (C5H5)TiCl(mu-S)2Pd(PEt3)2 2 and TiCl2(S)(mu-S)2Pd2(PEt3)4 3 along with silicon-sulfur bond cleavage, respectively. |
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