Stereoselective cycloadditions of chiral acyl-nitroso compounds; selective reactions of ring-cleaved cycloadducts leading to a new approach to polyoxamic acid |
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| Authors: | Pepper Adrian G Procter Garry Voyle Martyn |
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| Institution: | Department of Chemistry and Applied Chemistry, University of Salford, Salford, UK M5 4WT. |
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| Abstract: | Diesters obtained from diacids produced by oxidative ring cleavage of cycloadducts derived from acyl-nitroso compounds and cyclic 1,3-dienes undergo highly regioselective hydrolysis on reaction with lithium hydroperoxide, which allows for easy differentiation of the carboxyl groups leading to a new approach to polyoxamic acid. |
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