Impact of Pd-mordenite pretreatment on the heterogeneity of Heck catalysis |
| |
Authors: | Dams M Drijkoningen L De Vos D Jacobs P |
| |
Institution: | Kasteelpark Arenberg 23, 3001 Leuven, Belgium. |
| |
Abstract: | In Heck reactions with tributylamine as the base and in toluene, Pd(NH3)4(2+)-mordenite (0.4 wt% Pd) and Pd0-mordenite (0.4 and 4 wt% Pd) are not only active and selective, but also truly heterogeneous catalysts, while oxidized PdII species in an all-oxygen environment, i.e. ionic Pd2+ or PdO, are prone to leaching. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|