Synthesis,biological and physicochemical properties of Zinc(II) salicylate and 5-chlorosalicylate complexes with theophylline and urea |
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| Authors: | Zuzana Bujdo?ová Katarína Gy?ryová Jana Ková?ová Daniela Hudecová Ladislav Halás |
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| Institution: | 1.Department of Inorganic Chemistry,P.J. ?afárik University,Ko?ice,Slovak Republic;2.Institute of Macromolecular Chemistry, AV ?R,Prague,Czech Republic;3.Department of Biochemistry and Microbiology,Slovak Technical University,Bratislava,Slovak Republic |
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| Abstract: | New zinc(II) salicylate complex compounds of general formula (X-C6H3-2-(OH)COO)2Zn · Ln · xH2O (where X = H, 5-Cl; L = theophylline, urea; n = 2, 4; x = 1, 2, 4) were prepared and their thermal, spectral and biological properties were studied. It was found that the thermal
decomposition of hydrated compounds starts with the release of water. During the thermal decomposition of anhydrous compounds,
the release of salicylic acid, theophylline, urea, CO2, H2O and C6H5Cl takes place. Zinc oxide was found as the final product of the thermal decomposition heated up to 900 °C. The complexes
were tested against bacteria, yeasts and filamentous fungi. The highest biological activity show 5-chlorosalicylate compounds. |
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