The syntheses and photophysical properties of 4,4′-isopropylidendioxydiphenyl substituted ball-type dinuclear Mg(II) and Zn(II) phthalocyanines |
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Authors: | Mevlü de Canl?ca,Tebello Nyokong |
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Affiliation: | a Yildiz Technical University, Chemistry Department, Inorganic Chemistry Division, Davutpasa Campus, 34220 Esenler, Istanbul, Turkey b Rhodes University, Chemistry Department, P.O. Box 6140, Grahamstown, South Africa |
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Abstract: | The syntheses of ball-type dinuclear Zn(II) and Mg(II) phthalocyanines containing four 4,4′-isopropylidendioxydiphenyl substituents at the peripheral and non-peripheral positions are presented. The structures of the synthesized compounds were characterized using elemental analyses, and UV-Vis, FT-IR, 1H NMR and mass spectroscopies. The ΦF values were 0.14, 0.11, 0.22, 0.15 and ΦT values were 0.84, 0.88, 0.62, 0.74, for 6-9, respectively. The largest triplet yields were observed for the non-peripherally substituted complexes 6 and 7, showing that non-peripheral substitution favors increased population of the triplet state. All complexes showed reasonably long triplet lifetimes with τT 510, 310, 910 and 350 μs in DMSO, respectively. |
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Keywords: | Mg ball-type phthalocyanine Zn ball-type phthalocyanine Photodynamic therapy Non-peripheral phthalocyanine Triplet quantum yield |
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