Synthesis, characterization and molecular structures of barium(II) trichloroacetate DME/1,4-dioxane compounds |
| |
| Authors: | Sukhjinder Singh Deepika SainiS.K. Mehta Ravneet KaurValeria Ferretti |
| |
| Affiliation: | a Department of Chemistry and Centre of Advanced Studies in Chemistry, Panjab University, Chandigarh 160 014, India
b Centro di Strutturistica Diffrattometrica and Dipartimento di Chimica, University of Ferrara, Via L. Borsari 46, I-44121 Ferrara, Italy |
| |
| Abstract: | Two new barium(II) trichloroacetate compounds, [Ba(H2O)(DME)(μ-O2CCCl3)2]n (1) and [{Ba(H2O)2(diox)0.5(μ-O2CCCl3)2}(diox)]n (2) were synthesized and characterized by elemental analyses, physiochemical studies, FT-IR, 1H NMR, thermogravimetric analyses (TG/DTG/DSC) and single crystal X-ray studies. The reaction of hydrated barium(II) trichloroacetate monohydrate with excess DME (1,2-dimethoxyethane) and diox (1,4-dioxane) in methanol at room temperature led to the isolation of the novel compounds 1 and 2, respectively. Bridging trichloroacetate groups are anticipated on the basis of FT-IR studies and this was confirmed by the X-ray studies. Both compounds dissociate to produce ions in water, as shown by molar conductance values. 1H NMR spectroscopy confirms that DME and 1,4-dioxane are coordinated to the metal ion in these compounds. Single crystal X-ray diffraction studies reveal that the barium cation is coordinated to nine O atoms in a deformed coordination polyhedron in both compounds. Structural data of barium(II) trichloroacetates compounds have been obtained for the first time in the present investigation. |
| |
| Keywords: | Trichloroacetates DME 1,4-Dioxane Barium X-ray structure |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
