| O-乙基硫代磷酰二氯合成反应的动力学参数测定及条件选择 |
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| 引用本文： | 彭盘英,蒋彩云,王玉萍.O-乙基硫代磷酰二氯合成反应的动力学参数测定及条件选择[J].应用化学,2001,18(3):257-0. |
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| 作者姓名： | 彭盘英 蒋彩云 王玉萍 |
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| 作者单位： | 南京师范大学 |
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| 摘 要： | 反应动力学;O-乙基硫代磷酰二氯合成反应的动力学参数测定及条件选择
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| 关 键 词： | 反应动力学 O-乙基硫代磷酰二氯合成反应的动力学参数测定及条件选择 |
| 文章编号： | 1000-0518(2001)03-0257-03 |
| 收稿时间： | 2009-06-29 |
| 修稿时间： | 2000年6月27日 |
Synthesis of
O-Ethyldichlorothiophosphate and The Reaction Kinetics |
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| PENG Pan Ying ,JIANG Cai Yun,WANG Yu Ping.Synthesis of
O-Ethyldichlorothiophosphate and The Reaction Kinetics[J].Chinese Journal of Applied Chemistry,2001,18(3):257-0. |
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| Authors: | PENG Pan Ying JIANG Cai Yun WANG Yu Ping |
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| Institution: | PENG Pan Ying *,JIANG Cai Yun,WANG Yu Ping |
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| Abstract: | The O-ethyldichlorothiophosphate has been synthesized fromthiophosphoryl chloride and ethyl alcohol. The reaction order，preexponential factor, activation energy and rate constant of the reaction are determined. At the condition of n(ethyl alcohol)∶n(thiophosphoryl chloride)=3∶1, 10 ℃ and 2 h, the reaction gave O-ethyldichlorothiophosphate in yield more than 99.7%. |
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| Keywords: | ethyldichlorothiophosphate synthesis reaction kinctics |
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