Abnormal coordination of Arduengo's carbene upon reaction with M(3)(CO)(12) (M = Ru, Os) |
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Authors: | Crittall Matthew R Ellul Charles E Mahon Mary F Saker Olly Whittlesey Michael K |
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Affiliation: | Department of Chemistry, University of Bath, Claverton Down, Bath, UKBA2 7AY. m.k.whittlesey@bath.ac.uk. |
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Abstract: | The first examples of abnormal coordination of Ardeungo's carbene, 1,3-bis-adamantylimidazol-2-ylidene, have been isolated and structurally characterised following reaction of the free carbene with the trinuclear clusters M(3)(CO)(12) (M = Ru, Os). |
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