Allylation of prochiral C-nucleophiles catalyzed by the Pd(0)—(<Emphasis Type="Italic">S</Emphasis>)-(—)-BINAP complex |
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| Authors: | A V Lozanova T M Ugurchieva V V Veselovsky |
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| Institution: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation |
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| Abstract: | The allylation of prochiral C-nucleophiles catalyzed by the Pd(0)—(S)-(—)-BINAP complex (BINAP is 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl) was studied. The enantioselectivity of the allylation
was found to be low.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1753—1755, August, 2008. |
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| Keywords: | allylation C-nucleophiles palladium complexes phosphines |
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