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Site‐Selective 1,2‐Dicarbofunctionalization of Vinyl Boronates through Dual Catalysis
Authors:Shang‐Zheng Sun  Yaya Duan  Riccardo S Mega  Rosie J Somerville  Ruben Martin
Abstract:A modular, site‐selective 1,2‐dicarbofunctionalization of vinyl boronates with organic halides through dual catalysis is described. This reaction proceeds under mild conditions and is characterized by excellent chemo‐ and regioselectivity. It thus represents a complementary new technique for preparing densely functionalized alkyl boron architectures from simple and accessible precursors.
Keywords:dicarbofunctionalization  dual catalysis  homogeneous catalysis  Ni  radical reactions
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