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DESs: Green solvents for transition metal catalyzed organic reactions
Authors:Lifen Peng  Zhifang Hu  Qichao Lu  Zilong Tang  Yinchun Jiao  Xinhua Xu
Institution:1. Key Laboratory of Theoretical Organic Chemistry and Functional Molecule of Ministry of Education, Hunan Provincial Key Laboratory of Controllable Preparation and Functional Application of Fine Polymers, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China;2. State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
Abstract:In this review, the recent development about using DESs as green solvents in transition metal catalyzed organic reactions was highlighted. Firstly, the development of DESs was simply introduced. After presenting the advantages of DESs, transition metals catalyzed organic reactions using DESs as green solvents were classified and introduced in detail. Different transition metals such as Au, metal impregnated on magnetite, Pd and Ru catalyzed organic reactions proceeded smoothly in DESs and gave corresponding products in good yields. And in some cases, the catalytic systems could be recycled up to several times without any decrease in activity.
Keywords:Corresponding authors    DESs  Green solvents  Green chemistry  Transition metal  Catalysis
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