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A facile green synthesis of silver nanoparticles: An investigation on catalytic hydroxylation studies for efficient conversion of aryl boronic acids to phenol
Authors:Venu Kandula  Uppu Nagababu  Manoranjan Behera  Satyanarayana Yennam  Anindita Chatterjee
Affiliation:1. Department of Chemistry, Koneru Lakshmaiah Education Foundation, Vaddeswaram, Guntur, Andhra Pradesh 522502, India;2. Medicinal Chemistry Department, GVK Biosciences Pvt. Ltd., Nacharam, Hyderabad, Telangana 500076, India
Abstract:Ag nanoparticles (AgNPs) catalyst material is bio-synthesized and fully examined using various spectroscopy and microscopy techniques. Further this synthesized material is used for hydroxylation reaction, for this purpose we developed a simple and versatile bio-based method from aryl boronic acids to phenol. The reaction was studied in the presence of low cost ligand in a hydrated reaction medium without any hazardous organic solvents, as a result a finite amount of yield was achieved in short time (<15 min). The hydroxylation reaction is further carried out in a series of different arenes substituted samples with good amount of yields.
Keywords:Corresponding author.  AgNPs  Bio-synthesis  Catalyst  Hydroxylation  Boronic acid  Phenol
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