Reactivity of 1-Bromomethyl-2-lithio-o-carborane and Syntheses Based Thereon |
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| Authors: | Semioshkin A A Vichuzhanin M V Lysenko K A Bregadze V I |
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| Institution: | (1) Nesmeyanov Institute of Organometallic Compounds, ul. Vavilova 28, Moscow, 119334, Russia |
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| Abstract: | 1-Bromomethyl-o-carborane reacts at low temperature with lithium diisopropylamide to form 1-bromomethyl-2-lithio-o-carborane in quantitative yield. Reactions of the latter with various electrophiles give disubstituted carboranes in good yields. |
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