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Formation mechanism of ethanol-water excimer
Authors:Ying Liu  Hua Shao  Xiaowu Ni  Jian Lu
Abstract:The fluorescent spectrum and the excitation spectrum were used to present the cluster molecular structure feature in ethanol-water solutions.Through analyzing the fluorescent characteristics of an excimer,it is proposed that the excimers are formed between the ethanol-water cluster molecules in the excited state and in the ground state.The fluorescent lifetime and the fluorescent intensity decay process give information about the photo-physical and photo-chemical processes of the formation and the dissociation of an excimer.The theoretical calculation and physical analysis coincide with the experimental results.The preliminary conclusion about the structure feature of ethanol-water cluster molecule is that it has a planar one like a sandwich.
Keywords:excimer  mechanism  molecule  planar  like  sandwich  theoretical calculation  physical analysis  experimental  results  fluorescent lifetime  fluorescent intensity  decay  processes  information  dissociation  excited state  ground state  analyzing  characteristics
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