| 稀土与N-对甲基苯磺酰甘氨酸和邻菲咯啉配合物的合成与晶体结构 |
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| 引用本文： | 张漫波,胡瑞祥,梁福沛,马录芳,周忠远. 稀土与N-对甲基苯磺酰甘氨酸和邻菲咯啉配合物的合成与晶体结构[J]. 中国化学, 2005, 23(9): 1139-1142. DOI: 10.1002/cjoc.200591139 |
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| 作者姓名： | 张漫波 胡瑞祥 梁福沛 马录芳 周忠远 |
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| 作者单位： | [1]Department of Chemistry, Guangxi Normal University, Guilin, Guangxi, 541004 China [2]Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Kong, China |
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| 基金项目： | Project supported by Guangxi Provincial Education Foundation of China and Natural Science Foundation of Guangxi Province （No. 0229004）. |
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| 摘 要： | Three new lanthanide complexes with the formulae [Eu2（TsGly）6（phen）2（H2O）2] （1）, [Ln（TsGly）2（phen）2-（H2O）2]C1·2H2O [Ln=Er（2a） and Yb （2b）, TsGly=N-p-tolylsulfonylglycinate, phen= 1,10-phenanthroline] were synthesized. Crystallographic data for 1： monoclinic, P21/n, a= 1.29791（16） nm, b= 1.9034（2） nm, c= 1.7596（2） nm,β=93.410（3）°, V=4.3394（9） nm^3, Z=4, R1 =0.0326, wR2=0.0771; and for 2b： triclinic, P1, a= 1.2674（2） nm, b= 1.4405（2） nm, c= 1.4809（3） nm, a= 113.256（3）°, β= 108.253（3）°, γ=94.739（3）°, V=2.2922（7） nm°3, Z=2, R1=0.0292, wR2=0.0669. X-ray diffractional analysis reveals that compound 1 adopts dinuclear structure with fourfold bridging TsGly ligands between the Eu（Ⅲ） centers, while compound 2b features an unusual mononuclear structure.
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| 关 键 词： | 稀土元素 1，10-邻二氮杂菲 合成方法 单斜晶系 氨基酸 |
| 收稿时间： | 2005-03-16 |
| 修稿时间： | 2005-03-162005-06-21 |
Synthesis and Structures of Lanthanide Complexes of N-p-Tolylsulfonylglycinate and 1 ,10-Phenanthroline |
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| ZHANG Man-Bo,HU Rui-Xiang,LIANG Fu-Pei,MA Lu-Fang,ZHOU Zhong-Yuan. Synthesis and Structures of Lanthanide Complexes of N-p-Tolylsulfonylglycinate and 1 ,10-Phenanthroline[J]. Chinese Journal of Chemistry, 2005, 23(9): 1139-1142. DOI: 10.1002/cjoc.200591139 |
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| Authors: | ZHANG Man-Bo HU Rui-Xiang LIANG Fu-Pei MA Lu-Fang ZHOU Zhong-Yuan |
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| Abstract: | Three new lanthanide complexes with the formulae [Eu2(TsGly) 6(phen) 2(H2O) 2] ( 1 ), [Ln(TsGly) 2(phen) 2(H2O) 2]Cl · 2H2O [Ln=Er ( 2a ) and Yb ( 2b ), TsGly?N‐p‐tolylsulfonylglycinate, phen?1,10‐phenanthroline] were synthesized. Crystallographic data for 1 : monoclinic, P21/n, a=1.29791(16) nm, b&=1.9034(2) nm, c=1.7596(2) nm, β=93.410(3) °, V=4.3394(9) nm3, Z=4, R1=0.0326, wR2=0.0771; and for 2b : triclinic, P1, a=1.2674(2) nm, b=1.4405(2) nm, c=1.4809(3) nm, α=113.256(3) °, β=108.253(3) °, γ=94.739(3) °, V=2.2922(7) nm3, Z?2,R1=0.0292, w R2=0.0669. X‐ray diffractional analysis reveals that compound 1 adopts dinuclear structure with fourfold bridging TsGly ligands between the Eu(III) centers, while compound 2b features an unusual mononuclear structure. |
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| Keywords: | lanthanide N-protected amino acid 1 10-phenanthroline crystal structure |
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