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Synthesis of zinc oxide nanostructures catalytically active in the optical range without irradiation
Authors:M M Kasumov
Institution:1. Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. Palladina 32/34, Kiev, 03680, Ukraine
Abstract:A technique for synthesizing catalytically active zinc oxide-based nanostructures is described. The synthesis product represents a blue-gray powder. When it is introduced into a water solution of methyl orange the latter bleaches out both under daylight and in the dark. The activity of the material is measured by the Kubelka-Munk formula in the wavelength range 0.3–1.8 μm. As follows from X-ray phase analysis data, the synthesized material is a composite consisting of hexagonal structures with the parameters ZnO a: 3.2491, c: 5.2046] and Zn a: 2.6639, c: 4.9397]. A mechanism underlying the formation of a ZnO-Zn nanocomposite is suggested.
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