Sequential determination of actinide isotopes and radiostrontium in swipe samples

Assays of alpha- and beta-emitting radionuclides in swipe samples are often required to monitor the presence of removable surface contamination for radiological protection and control in nuclear facilities. Swipe analysis has also proven to be a very sensitive analytical technique to detect nuclear signatures for safeguard verification purposes. A new sequential method for the determination of actinide isotopes and radiostrontium in swipe samples, which utilizes a streamlined column separation with stacked anion and extraction chromatography resins, has been developed. To validate the separation procedure, spike and blank samples were prepared and analyzed by inductively coupled mass spectrometry (ICP-MS), alpha spectrometry and liquid scintillation (LS) counting. Low detection limits have been achieved for isotopic analysis of Pu (²³⁸Pu, ²³⁹Pu, ²⁴⁰Pu, ²⁴¹Pu), U (²³⁴U, ²³⁵U, ²³⁸U), Am (²⁴¹Am), Cm (²⁴²Cm, ^243/244Cm) and Sr (⁹⁰Sr) at ultra-trace concentration levels in swipe samples.