| 4-乙酰氨基-4’-甲基丙烯酰氨基-二苯基甲烷的合成及其聚合 |
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| 引用本文： | 丘坤元,鲁志华.4-乙酰氨基-4’-甲基丙烯酰氨基-二苯基甲烷的合成及其聚合[J].高分子学报,1991,0(6):753-756. |
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| 作者姓名： | 丘坤元 鲁志华 |
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| 作者单位： | 北京大学化学系 10087l |
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| 摘 要： |
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| 关 键 词： | AMDPM 甲烷 自由基 共聚合 DADPM |
| 收稿时间： | 1991-05-16 |
SYNTHESIS OF 4-ACETAMINO-4'-METHACRYLOYLAMINO-DIPHENYLMETHANE AND ITS POLYMERIZATION |
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| QIU Kun-yuan,LU Zhi-hua.SYNTHESIS OF 4-ACETAMINO-4''-METHACRYLOYLAMINO-DIPHENYLMETHANE AND ITS POLYMERIZATION[J].Acta Polymerica Sinica,1991,0(6):753-756. |
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| Authors: | QIU Kun-yuan LU Zhi-hua |
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| Institution: | Department of Chemistry; Peking University; Beijing; Post code: 100871 |
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| Abstract: | 4-Acetamino-4'-methacryloylaminodiphenylmethane (AMDPM) monomer was synthesized from 4,4'-diaminodiphenylmethane via acetylation reaction and then reacted with methacryloyl chloride. AMDPM monomer was characterized by elemental analysis,1H-NMR and IR spectra. In the presence of 2,2'-azobisisobutyronitrile (AIBN) AMDPM polymerized and formed a brittle homopolymer. The copolymers of methyl acrylate(MA) with AMDPM in various molar ratio were synthesized via free radical polymerization in N,N-dimethylformamide solution.The monomer reactivity ratios were determined by Fineman-Ross method. |
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