| Spectroelectrochemical studies of [Mo(dtc)_4][Eu(dtc)_4] and [Mo(dtc)_4][Er(dtc)_4] |
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| 作者姓名： | ZHAO Yu-E FU Qing-Hong ZHANG Heng-Bin LI Shu-Jia SUN Chun-Ting SUN Chia-Chung |
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| 作者单位： | ZHAO，Yu-E FU，Qing-Hong ZHANG，Heng-Bin LI，Shu-Jia SUN，Chun-Ting SUN，Chia-ChungDepartment of Chemistry and Institute of Theoretical Chemistry，Jilin University，Changchun，Jilin 130023，China |
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| 摘 要： | Redox and spectroscopic properties of the eight-coordination complexes of molybdenum and the rare-earth elements Eu or Er with N,N-diethyldithiocarbamate (dtc) were characterised by cyclic voltamrnetry and UV-visible absorption spectra.The complex cation Mo(dtc)4]+ is more stable than the complex anions Eu(dtc)4]-and Er(dtc)4]-in redox processes,and possesses good redox reversibility.The electron transfer number,formal standard electrode potential in the redox process for the complex cation and its diffusion coefficients were obtained by in aitu spectroelectro-chemistry.
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Spectroelectrochemical studies of [Mo(dtc)_4][Eu(dtc)_4] and [Mo(dtc)_4][Er(dtc)_4] |
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| ZHAO,Yu-E FU,Qing-Hong ZHANG,Heng-Bin LI,Shu-Jia SUN,Chun-Ting SUN,Chia-Chung.Spectroelectrochemical studies of [Mo(dtc)_4][Eu(dtc)_4] and [Mo(dtc)_4][Er(dtc)_4][J].Chinese Journal of Chemistry,1997,15(4):318-326. |
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| Authors: | ZHAO Yu-E FU Qing-Hong ZHANG Heng-Bin LI Shu-Jia SUN Chun-Ting SUN Chia-Chung |
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| Institution: | ZHAO,Yu-E FU,Qing-Hong ZHANG,Heng-Bin LI,Shu-Jia SUN,Chun-Ting SUN,Chia-ChungDepartment of Chemistry and Institute of Theoretical Chemistry,Jilin University,Changchun,Jilin 130023,China |
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| Abstract: | Redox and spectroscopic properties of the eight-coordination complexes of molybdenum and the rare-earth elements Eu or Er with N,N-diethyldithiocarbamate (dtc) were characterised by cyclic voltamrnetry and UV-visible absorption spectra.The complex cation Mo(dtc)4]+ is more stable than the complex anions Eu(dtc)4]-and Er(dtc)4]-in redox processes,and possesses good redox reversibility.The electron transfer number,formal standard electrode potential in the redox process for the complex cation and its diffusion coefficients were obtained by in aitu spectroelectro-chemistry. |
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| Keywords: | Molybdenum rare earth redox UV-visible spectra |
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