| 微波辐射超稳Y沸石负载硅钨酸催化合成肉桂酸β-苯乙酯 |
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| 引用本文： | 袁先友,阳年发,刘跃进.微波辐射超稳Y沸石负载硅钨酸催化合成肉桂酸β-苯乙酯[J].广州化学,2005,30(3):18-21. |
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| 作者姓名： | 袁先友 阳年发 刘跃进 |
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| 作者单位： | 1. 湖南科技学院化学系,湖南,永州,425006;湘潭大学化学化工学院,湖南,湘潭,411105
2. 湘潭大学化学化工学院,湖南,湘潭,411105 |
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| 基金项目： | 湖南省教育厅重点资助项目(02A042)，湖南省自然科学基金项目(04JJ40018) |
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| 摘 要： | 在微波辐射下,以超稳Y沸石负载硅钨酸(HSW/USY)为催化剂,不使用溶剂,合成了肉桂酸β-苯乙酯。其优化反应条件是:负载量为20%的HSW/USY催化剂1.2 g,肉桂酸27 mmol,β-苯乙醇43 mmol,微波辐射功率600 W,辐射时间10 min,产率达91.5%。产物经过红外光谱表征。
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| 关 键 词： | 微波辐射 超稳Y沸石负载硅钨酸 催化 合成 肉桂酸β-苯乙酯 |
| 文章编号： | 1009-220X(2005)03-0018-04 |
| 修稿时间： | 2004年10月9日 |
Synthesis of β-Phenylethyl Cinnamate Catalyzed by Ultra Stable Y Zeolite Supported Silicotungstic Acid under Microwave Irradiation |
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| YUANXian-you,YANG Nian-fa,LIU Yue-jin.Synthesis of β-Phenylethyl Cinnamate Catalyzed by Ultra Stable Y Zeolite Supported Silicotungstic Acid under Microwave Irradiation[J].Guangzhou Chemistry,2005,30(3):18-21. |
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| Authors: | YUANXian-you YANG Nian-fa LIU Yue-jin |
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| Institution: | YUAN Xian-you1,2,YANG Nian-fa2,LIU Yue-jin2 |
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| Abstract: | β-Phenylethyl cinnamate was synthesized from cinnamic acid with β-phenylethyl alcohol using ultra stable Y zeolite supported silicotungstic acid (HSW/USY) as catalysts without solvent under microwave irradiation. Under the optimum reaction conditions, HSW/USY (loaded amount 20%) 1.2 g, cinnamic acid 27 mmol, β-phenethyl alcohol 43 mmol, microwave power 600 W, microwave irradiation time 10 min), the yield of ester was 91.5%. The product was characterized by IR. |
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| Keywords: | microwave irradiation ultra stable Y zeolite supported silicotungstic acid catalysis β-phenlyethly cinnamate esterification |
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