| 晶态层状苯乙胺-N，N-双甲基膦酸锆的合成及层间距异常分析 |
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| 引用本文： | 邹晓川,傅相锴,李跃东,龚必伟,陈俊显,涂小波.晶态层状苯乙胺-N，N-双甲基膦酸锆的合成及层间距异常分析[J].无机化学学报,2009,25(2):290-295. |
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| 作者姓名： | 邹晓川 傅相锴 李跃东 龚必伟 陈俊显 涂小波 |
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| 作者单位： | 西南大学化学化工学院,应用化学研究所,重庆,400715;重庆市应用化学市级重点实验室,重庆,400715 |
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| 基金项目： | 重庆市高校重点实验室建设基金 |
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| 摘 要： | 本文用氢氟酸络合法合成了高结晶度的苯乙胺-N,N-双甲基膦酸锆(ZBEDP),用1H NMR、31p NMR、FTIR、TG-DSC、XRD和SEM对其进行了结构表征和形貌分析.热重研究表明该化合物具有较好的热稳定性,直到400℃层状结构才开始破坏.XRD和SEM结果表明ZBEDP具有典型的层状结构,其层间距(1.70 nm)比α-ZrP(0.76nm)增加了0.94 nm.有趣的是ZBEDP的层间距比少一个C原子的苄胺-N,N-双甲基膦酸锆(ZBMDP)减少了0.06 nm,与烷胺双膦酸锆的层间距线性关系相反.ZBEDP层间距反常现可能是-NCH2CH2C6H5部分在层板间的空间排列不同于ZBMDP所致.
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| 关 键 词： | 苯乙胺 苯乙胺-NN-双甲基膦酸 苯乙胺-NN-双甲基膦酸锆 层状化合物 层间距 |
Synthesis of Crystalline Layered Zirconium Phenylethylamino-N,N-bis Methylphosphonates and Analysis for Its Novel Interlayer Distance |
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| ZOU Xiao-Chuan,FU Xiang-Kai,LI Yue-Dong,GONG Bi-Wei,CHEN Jun-Xian and TU Xiao-Bo.Synthesis of Crystalline Layered Zirconium Phenylethylamino-N,N-bis Methylphosphonates and Analysis for Its Novel Interlayer Distance[J].Chinese Journal of Inorganic Chemistry,2009,25(2):290-295. |
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| Authors: | ZOU Xiao-Chuan FU Xiang-Kai LI Yue-Dong GONG Bi-Wei CHEN Jun-Xian and TU Xiao-Bo |
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| Institution: | Research Institute of Applied Chemistry,College of Chemistry and Chemical Engineering, Southwest China University, Chongqing 400715; Key Laboratory of Applied Chemistry of Chongqing Municipality, Chongqing 400715,Research Institute of Applied Chemistry,College of Chemistry and Chemical Engineering, Southwest China University, Chongqing 400715; Key Laboratory of Applied Chemistry of Chongqing Municipality, Chongqing 400715,Research Institute of Applied Chemistry,College of Chemistry and Chemical Engineering, Southwest China University, Chongqing 400715; Key Laboratory of Applied Chemistry of Chongqing Municipality, Chongqing 400715,Research Institute of Applied Chemistry,College of Chemistry and Chemical Engineering, Southwest China University, Chongqing 400715; Key Laboratory of Applied Chemistry of Chongqing Municipality, Chongqing 400715,Research Institute of Applied Chemistry,College of Chemistry and Chemical Engineering, Southwest China University, Chongqing 400715; Key Laboratory of Applied Chemistry of Chongqing Municipality, Chongqing 400715 and Research Institute of Applied Chemistry,College of Chemistry and Chemical Engineering, Southwest China University, Chongqing 400715; Key Laboratory of Applied Chemistry of Chongqing Municipality, Chongqing 400715 |
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| Abstract: | |
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| Keywords: | phenylethylamine phenylethylamino-N N-bis-methylphosphonic zirconium phenylethylamino-N N-bis methylphosphonate layered compounds interlayer distance |
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