Ring opening of cyclic N,O-acetals with allyltrimethylsilane under Lewis acidic conditions |
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Authors: | Roderick W. Bates Yongna Lu Melody Peiling Cai |
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Affiliation: | Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, 21 Nanyang Link, Nanyang Technological University, Singapore 637371 |
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Abstract: | Five and six-membered cyclic N,O-acetals with N-carboxyalkyl and sulfonyl groups undergo clean and high yielding ring opening with allyltrimethylsilane in the presence of strong Lewis acids to give homoallylic amine derivatives. |
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