Vibrational Spectroscopic Study of [1,2-bis(4-pyridyl)ethane]metal(II) Tetracyanonickelate(II). 2 m-Xylene Clathrates |
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| Authors: | Yüksel Tufan Nurcan Karacan and Ümmühan Özdemr |
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| Institution: | (1) Fen-Edebiyat Fak. , Kimya Böl., Erciyes Üniversitesi, Yozgat, Turkey;(2) Fen-Edebiyat Fak., Kimya Böl, Gazi Üniversitesi, 06500 Ankara, Turkey |
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| Abstract: | Four new Hofmann-type clathrates of the form M(bpa)2Ni(CN)4· 2m-xylene (M = Mn , Fe , Co and Ni; bpa = 1,2-bis(4-pyridyl)ethane) have been synthesized and characterized by vibrational spectroscopy. The M(bpa)2Ni(CN)4 (M = Fe and Co) host structure is similar to the classical Hofmann-type host framework composed of layers of a two dimensional catena-metal tetra- -cyanonickelate(II) network, but in M(bpa)2Ni(CN)4 (M = Mn and Ni), the Ni(CN)4 moiety behaves as a bidentate –NC-Ni(CN)2-CN–]– unit in the host framework. |
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| Keywords: | Hofmann-type clathrate 1 2-bis(4-pyridyl)ethane m-xylene inclusion compounds IR and Raman Spectra |
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