Steady regimes of exothermic autocatalytic reaction in a continued stirred-tank reactor |
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| Authors: | B L Korsunskii N G Samoilenko E V Deyun A O Il’chenko |
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| Institution: | (1) Institute of New Chemical Problems, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia;(2) Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 117977, Russia;(3) Moscow Engineering Physics Institute (Technical University), Kashirskoe sh. 31, Moscow, 115409, Russia |
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| Abstract: | A continued stirred-tank reactor with an exothermic autocatalytic reaction running in it is modeled. In contrast to the simple kinetic law formulated in terms of a first-order equation, a variety of possible types of thermal isoclines, including isoles, are found for the autocatalytic process in the dimensionless “degree of conversion-temperature” coordinates. A bifurcation curve separating the domains of existence of one and three steady states is constructed in the Se-Da coordinates. |
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