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Switching catalytic reaction conducted in pore void of mesoporous material by redox gate control
Authors:Fujiwara Masahiro  Terashima Shigeki  Endo Yasuko  Shiokawa Kumi  Ohue Hiroyoshi
Affiliation:Kansai Center, National Institute of Advanced Industrial Science and Technology (AIST), 1 Midorigaoka, Ikeda, Osaka 563-8577, Japan. m-fujiwara@aist.go.jp
Abstract:A molecular gate attached on the pore outlet of a mesoporous material, which is opened and closed by redox system of thiol groups, effectively switched the progress of a catalytic reaction promoted by the acidic site in the pore void.
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