The use of SO2Cl2 in organometallic chemistry. Convenient high yield syntheses of [Fe(η-C5H5)(CO)3] [FeCl4] and [M(CO5Cl] (M = Mn or Re) |
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| Authors: | AR Manning Gerald McNally Reg Davis Christopher C Rowland |
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| Institution: | Department of Chemistry, University College, Belfield, Dublin 4 Ireland;School of Chemical and Physical Sciences, Kingston Polytechnic, Penrhyn Road Kingston-upon-Thames, KT1 2EE Great Britain |
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| Abstract: | Depending on the substrate and the reaction conditions, SO2Cl2 is a useful reagent which brings about either chlorination or the formation of cationic species on reaction with transition metal carbonyl complexes. |
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