Darstellung und eigenschaften von und reaktionen mit metallhaltigen heterocyclen: XXXIII. Synthese und kristallstruktur von (μ3-thio)(μ3-organophosphido)tris(tricarbonyleisen)-(2Fe-Fe)-komplexen |
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Authors: | Ekkehard Lindner Gerhard A. Weiss Wolfgang Hiller Riad Fawzi |
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Affiliation: | Institut für Anorganische Chemie der Universitiät, Auf der Morgenstelle 18, D-7400 Tübingen 1 B.R.D. |
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Abstract: | The cluster compounds (μ3-S)(μ3-PR)Fe3(CO)9 are obtained by reaction of the dichloroorganylphosphane sulphides RP(S)Cl2 (R = CH3, 4-CH3OC6H4, C6H5) with Na2[Fe(CO)4] in ether under cleavage of the PS bond. On the basis of X-ray crystallographic determinations the iron clusters crystallize for R = 4-CH3OC6H4 and C6H5 in the monoclinic and triclinic space group C2/c and P with Z = 8 and 4, respectively. |
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