Thermal decomposition reactions of amminecobalt(III)complexes |
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Authors: | E Ingier-Stocka |
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Institution: | (1) Institute of Inorganic Chemistry and Metallurgy of Rare Elements, Technical University of Wroc aw, 50-370 Wroc aw, Poland |
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Abstract: | Simultaneous TG-DTG-DTA studies under non-isothermal conditions on Co(NH3)6]Cl3, Co(NH3)5]Cl2 and Co(NH3)]2(C2O4)3.4H2O complexes have been carried out in air and argon atmospheres in the temperature range 293–1273 K. All the dissociation processes occur in three main stages. The kinetics of thermal decomposition of the complexes have been evaluated from the dynamic weight loss data, to determine the most probably mechanisms of the stages on the basis of statistical analysis. The decomposition of the compounds was controlled by diffusion and phase boundary reactions except stage III of the oxalate complex in argon (random nucleation). The activation energiesE
a of the particular stages of the thermal decomposition were calculated.
Zusammenfassung Simultane TG-DTG-DTA-Untersuchungen an den Komplexverbindungen Co(NH3)6]Cl3, Co(NH3)5Cl]Cl2 und Co(NH3)6]2(C2O4)3.4H2O unter nichtisothermen Bedingungen wurden in Luft und Argonatmosphäre bei 293–1273 K durchgeführt. Die Zersetzung läuft in jeweils drei Stufen ab. Für die kinetische Auswertung der thermischen Zersetzung der Komplexverbindungen aus den dynamischen Gewichtsabnahmekurven wurde der wahrscheinlichste Mechanismus der einzelnen Stufen mit Hilfe von statistischen Analysen ermittelt. Die Zersetzung der Komplexverbindungen wird meist durch Diffusions- und Phasengrenzreaktionen kontrolliert, nur bei der 3. Stufe des Oxalatkomplexes in Argon herrscht statistische Keimbildung. Die AktivierungsenergienE
a der einzelnen Zersetzungsstufen werden berechnet.
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![khcy](/content/j168104l05142j2h/xxlarge1093.gif) ![acy](/content/j168104l05142j2h/xxlarge1072.gif) ![ncy](/content/j168104l05142j2h/xxlarge1085.gif) ![icy](/content/j168104l05142j2h/xxlarge1080.gif) ![zcy](/content/j168104l05142j2h/xxlarge1079.gif) ![mcy](/content/j168104l05142j2h/xxlarge1084.gif) ![ocy](/content/j168104l05142j2h/xxlarge1086.gif) ![pcy](/content/j168104l05142j2h/xxlarge1087.gif) ![ocy](/content/j168104l05142j2h/xxlarge1086.gif) ![vcy](/content/j168104l05142j2h/xxlarge1074.gif) ![iecy](/content/j168104l05142j2h/xxlarge1077.gif) ![rcy](/content/j168104l05142j2h/xxlarge1088.gif) ![khcy](/content/j168104l05142j2h/xxlarge1093.gif) ![ncy](/content/j168104l05142j2h/xxlarge1085.gif) ![ocy](/content/j168104l05142j2h/xxlarge1086.gif) ![scy](/content/j168104l05142j2h/xxlarge1089.gif) ![tcy](/content/j168104l05142j2h/xxlarge1090.gif) ![rcy](/content/j168104l05142j2h/xxlarge1088.gif) ![acy](/content/j168104l05142j2h/xxlarge1072.gif) 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![acy](/content/j168104l05142j2h/xxlarge1072.gif) ![lcy](/content/j168104l05142j2h/xxlarge1083.gif) ![acy](/content/j168104l05142j2h/xxlarge1072.gif) ![tcy](/content/j168104l05142j2h/xxlarge1090.gif) ![ncy](/content/j168104l05142j2h/xxlarge1085.gif) ![ocy](/content/j168104l05142j2h/xxlarge1086.gif) ![gcy](/content/j168104l05142j2h/xxlarge1075.gif) ![kcy](/content/j168104l05142j2h/xxlarge1082.gif) ![ocy](/content/j168104l05142j2h/xxlarge1086.gif) ![mcy](/content/j168104l05142j2h/xxlarge1084.gif) ![pcy](/content/j168104l05142j2h/xxlarge1087.gif) ![lcy](/content/j168104l05142j2h/xxlarge1083.gif) ![iecy](/content/j168104l05142j2h/xxlarge1077.gif) ![kcy](/content/j168104l05142j2h/xxlarge1082.gif) ![scy](/content/j168104l05142j2h/xxlarge1089.gif) ![acy](/content/j168104l05142j2h/xxlarge1072.gif) ![rcy](/content/j168104l05142j2h/xxlarge1088.gif) ![gcy](/content/j168104l05142j2h/xxlarge1075.gif) ![ocy](/content/j168104l05142j2h/xxlarge1086.gif) ![ncy](/content/j168104l05142j2h/xxlarge1085.gif) , ![pcy](/content/j168104l05142j2h/xxlarge1087.gif) ![dcy](/content/j168104l05142j2h/xxlarge1076.gif) ![chcy](/content/j168104l05142j2h/xxlarge1095.gif) ![icy](/content/j168104l05142j2h/xxlarge1080.gif) ![ncy](/content/j168104l05142j2h/xxlarge1085.gif) ![yacy](/content/j168104l05142j2h/xxlarge1103.gif) ![yucy](/content/j168104l05142j2h/xxlarge1102.gif) ![shchcy](/content/j168104l05142j2h/xxlarge1097.gif) ![iecy](/content/j168104l05142j2h/xxlarge1077.gif) ![jcy](/content/j168104l05142j2h/xxlarge1081.gif) ![scy](/content/j168104l05142j2h/xxlarge1089.gif) ![mcy](/content/j168104l05142j2h/xxlarge1084.gif) ![iecy](/content/j168104l05142j2h/xxlarge1077.gif) ![khcy](/content/j168104l05142j2h/xxlarge1093.gif) ![acy](/content/j168104l05142j2h/xxlarge1072.gif) ![ncy](/content/j168104l05142j2h/xxlarge1085.gif) ![icy](/content/j168104l05142j2h/xxlarge1080.gif) ![mcy](/content/j168104l05142j2h/xxlarge1084.gif) ![pcy](/content/j168104l05142j2h/xxlarge1087.gif) ![rcy](/content/j168104l05142j2h/xxlarge1088.gif) ![ocy](/content/j168104l05142j2h/xxlarge1086.gif) ![icy](/content/j168104l05142j2h/xxlarge1080.gif) ![zcy](/content/j168104l05142j2h/xxlarge1079.gif) ![vcy](/content/j168104l05142j2h/xxlarge1074.gif) ![ocy](/content/j168104l05142j2h/xxlarge1086.gif) ![lcy](/content/j168104l05142j2h/xxlarge1083.gif) ![softcy](/content/j168104l05142j2h/xxlarge1100.gif) ![ncy](/content/j168104l05142j2h/xxlarge1085.gif) ![ocy](/content/j168104l05142j2h/xxlarge1086.gif) ![gcy](/content/j168104l05142j2h/xxlarge1075.gif) ![ocy](/content/j168104l05142j2h/xxlarge1086.gif) ![bcy](/content/j168104l05142j2h/xxlarge1073.gif) ![rcy](/content/j168104l05142j2h/xxlarge1088.gif) ![acy](/content/j168104l05142j2h/xxlarge1072.gif) ![ocy](/content/j168104l05142j2h/xxlarge1086.gif) ![vcy](/content/j168104l05142j2h/xxlarge1074.gif) ![acy](/content/j168104l05142j2h/xxlarge1072.gif) ![ncy](/content/j168104l05142j2h/xxlarge1085.gif) ![icy](/content/j168104l05142j2h/xxlarge1080.gif) ![tscy](/content/j168104l05142j2h/xxlarge1094.gif) ![iecy](/content/j168104l05142j2h/xxlarge1077.gif) ![ncy](/content/j168104l05142j2h/xxlarge1085.gif) ![tcy](/content/j168104l05142j2h/xxlarge1090.gif) ![rcy](/content/j168104l05142j2h/xxlarge1088.gif) ![ocy](/content/j168104l05142j2h/xxlarge1086.gif) ![kcy](/content/j168104l05142j2h/xxlarge1082.gif) ![rcy](/content/j168104l05142j2h/xxlarge1088.gif) ![icy](/content/j168104l05142j2h/xxlarge1080.gif) ![scy](/content/j168104l05142j2h/xxlarge1089.gif) ![acy](/content/j168104l05142j2h/xxlarge1072.gif) ![lcy](/content/j168104l05142j2h/xxlarge1083.gif) ![lcy](/content/j168104l05142j2h/xxlarge1083.gif) ![icy](/content/j168104l05142j2h/xxlarge1080.gif) ![zcy](/content/j168104l05142j2h/xxlarge1079.gif) ![acy](/content/j168104l05142j2h/xxlarge1072.gif) ![tscy](/content/j168104l05142j2h/xxlarge1094.gif) ![icy](/content/j168104l05142j2h/xxlarge1080.gif) . ![Vcy](/content/j168104l05142j2h/xxlarge1042.gif) ![ycy](/content/j168104l05142j2h/xxlarge1099.gif) ![chcy](/content/j168104l05142j2h/xxlarge1095.gif) ![icy](/content/j168104l05142j2h/xxlarge1080.gif) ![scy](/content/j168104l05142j2h/xxlarge1089.gif) ![lcy](/content/j168104l05142j2h/xxlarge1083.gif) ![iecy](/content/j168104l05142j2h/xxlarge1077.gif) ![ncy](/content/j168104l05142j2h/xxlarge1085.gif) ![ecy](/content/j168104l05142j2h/xxlarge1101.gif) ![ncy](/content/j168104l05142j2h/xxlarge1085.gif) ![iecy](/content/j168104l05142j2h/xxlarge1077.gif) ![rcy](/content/j168104l05142j2h/xxlarge1088.gif) ![gcy](/content/j168104l05142j2h/xxlarge1075.gif) ![icy](/content/j168104l05142j2h/xxlarge1080.gif) ![acy](/content/j168104l05142j2h/xxlarge1072.gif) ![tcy](/content/j168104l05142j2h/xxlarge1090.gif) ![icy](/content/j168104l05142j2h/xxlarge1080.gif) ![vcy](/content/j168104l05142j2h/xxlarge1074.gif) ![acy](/content/j168104l05142j2h/xxlarge1072.gif) ![tscy](/content/j168104l05142j2h/xxlarge1094.gif) ![icy](/content/j168104l05142j2h/xxlarge1080.gif) a ![ocy](/content/j168104l05142j2h/xxlarge1086.gif) ![tcy](/content/j168104l05142j2h/xxlarge1090.gif) ![dcy](/content/j168104l05142j2h/xxlarge1076.gif) ![iecy](/content/j168104l05142j2h/xxlarge1077.gif) ![lcy](/content/j168104l05142j2h/xxlarge1083.gif) ![softcy](/content/j168104l05142j2h/xxlarge1100.gif) ![ncy](/content/j168104l05142j2h/xxlarge1085.gif) ![ycy](/content/j168104l05142j2h/xxlarge1099.gif) ![scy](/content/j168104l05142j2h/xxlarge1089.gif) ![tcy](/content/j168104l05142j2h/xxlarge1090.gif) ![acy](/content/j168104l05142j2h/xxlarge1072.gif) ![dcy](/content/j168104l05142j2h/xxlarge1076.gif) ![icy](/content/j168104l05142j2h/xxlarge1080.gif) ![rcy](/content/j168104l05142j2h/xxlarge1088.gif) ![acy](/content/j168104l05142j2h/xxlarge1072.gif) ![zcy](/content/j168104l05142j2h/xxlarge1079.gif) ![lcy](/content/j168104l05142j2h/xxlarge1083.gif) ![ocy](/content/j168104l05142j2h/xxlarge1086.gif) ![zhcy](/content/j168104l05142j2h/xxlarge1078.gif) ![iecy](/content/j168104l05142j2h/xxlarge1077.gif) ![ncy](/content/j168104l05142j2h/xxlarge1085.gif) ![icy](/content/j168104l05142j2h/xxlarge1080.gif) .
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