Au(I) complexes-catalyzed transfer vinylation of alcohols and carboxylic acids |
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| Authors: | Aki Nakamura |
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| Institution: | Department of Chemistry, Graduate School of Science, Kyushu University, Higashi-ku, Fukuoka 812-8581, Japan Japan Science and Technology Agency (JST), CREST, Japan |
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| Abstract: | Au(I) complexes-catalyzed transfer vinylation of alcohols and carboxylic acids has been achieved. The catalyst system consists of 2 mol % AuClPPh3 and 2 mol % AgOAc. Primary alcohols and secondary alcohols were converted into corresponding vinyl ethers in good yield (64-93%); however, tertiary alcohols showed poor reactivities. Carboxylic acids were also transformed into corresponding vinyl esters in good yield (78-96%). |
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