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Synthesis of enantiopure ethyl deoxymonate B from allylic sulfinyl dihydropyrans |
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| Authors: | Roberto Fernández de la Pradilla Nadia Lwoff |
| Institution: | Instituto de Química Orgánica, CSIC, Juan de la Cierva, 3, 28006 Madrid, Spain |
| Abstract: | A completely stereoselective dihydroxylation of a dihydropyranol and a cross-metathesis in the presence of a free homoallylic hydroxyl group are the key steps of a synthesis of enantiopure ethyl deoxymonate B from a sulfinyl dienol. |
| Keywords: | Pseudomonic Acids Allylic Sulfoxides Sigmatropic rearrangement Stereoselective dihydroxylation |
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