On the interactions of N,N′-bismesitylimidazolin-2-yl and alcohols |
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| Authors: | Michael A Schmidt |
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| Institution: | Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA |
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| Abstract: | The interaction of N,N′-bismesitylimidazolin-2-yl (IMes) with alcohols is discussed. NMR spectroscopy and X-ray crystallography were used to examine the influence of solvent and alcohol on this interaction. The stabilizing effect of these interactions may be used for the storage of nitrogen-heterocyclic carbenes (NHCs) since removal of the volatiles liberates the NHC. |
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