| FeCl3.6H2O作用的a-羰基-a-乙酰/羧基二硫缩烯酮的脱乙酰/羧基反应 |
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| 引用本文： | 章学玉,于海丰,刁全平,殷家南,息春美,吴钺.FeCl3.6H2O作用的a-羰基-a-乙酰/羧基二硫缩烯酮的脱乙酰/羧基反应[J].化学通报,2016,79(5):459-462. |
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| 作者姓名： | 章学玉 于海丰 刁全平 殷家南 息春美 吴钺 |
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| 作者单位： | 鞍山师范学院化学与生命科学学院,鞍山师范学院化学与生命科学学院,鞍山师范学院化学与生命科学学院,鞍山师范学院化学与生命科学学院,鞍山师范学院化学与生命科学学院,鞍山师范学院化学与生命科学学院 |
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| 摘 要： | 探讨了价廉易得、环境友好和无毒性的FeCl3.6H2O作用的a-羰基-a-乙酰/羧基二硫缩烯酮的脱乙酰/羧基反应,高产率合成a-羰基二硫缩烯酮。该反应具有反应条件温和、环境友好和操作简单等优点。
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| 关 键 词： | 二硫缩烯酮 氯化铁 脱乙酰基反应 脱羧反应 |
| 收稿时间： | 2015/9/11 0:00:00 |
| 修稿时间： | 2015/10/21 0:00:00 |
FeCl3.6H2O-mediated Deacetylation/Decarboxylation of a-carbonyl-a-aceto/carboxyl Ketene Dithioacetals |
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| Zhang Xueyu,Yu Haifeng,Diao Quanping,Yin Jianan,Xi Chunmei and Wu Yue.FeCl3.6H2O-mediated Deacetylation/Decarboxylation of a-carbonyl-a-aceto/carboxyl Ketene Dithioacetals[J].Chemistry,2016,79(5):459-462. |
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| Authors: | Zhang Xueyu Yu Haifeng Diao Quanping Yin Jianan Xi Chunmei and Wu Yue |
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| Institution: | School of Chemistry and Life Science,Anshan Normal University,School of Chemistry and Life Science,Anshan Normal University,School of Chemistry and Life Science,Anshan Normal University,School of Chemistry and Life Science,Anshan Normal University,School of Chemistry and Life Science,Anshan Normal University,School of Chemistry and Life Science,Anshan Normal University |
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| Abstract: | An inexpensive and environmentally friendly FeCl3·6H2O-mediated deacetylation/decarboxylation of ?-carbonyl-?-aceto/carboxyl ketene dithioacetals had been developed. The procedure was characterized by mild reaction condition, environmentally benign and similicity. |
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| Keywords: | ketene dithioacetals iron (III) chloride deacetylation decarboxylation |
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