Cyclo-depolymerization of poly(propylene terephthalate): some ring-opening polymerizations of the cyclic oligomers produced |
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Authors: | Stephen D Kamau Philip Hodge Madeleine Helliwell |
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Institution: | Department of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, UK |
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Abstract: | We report the cyclo-depolymerization of poly(propylene terephthalate) to give a mixture of cyclic oligomers in 94% yield, the characterization of the mixture by 1H-NMR spectroscopy, matrix assisted laser desorption ionization time of flight mass spectrometry and gel permeation chromatography. The major cyclic oligomer in the mixture was shown to be the cyclic dimer. It was isolated and its X-ray crystal structure determined. Some entropically-driven ring-opening polymerizations of the cyclic oligomers were carried out. So too were some copolymerizations using mixtures of the cyclic oligomers and those derived similarly from poly(ethylene terephthalate) and poly(butylene terephthalate). 13C-NMR spectroscopic analysis showed that the copolymers were random. Copyright © 2003 John Wiley & Sons, Ltd. |
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Keywords: | poly(propylene terephthalate) cyclo-depolymerization macrocycles ring-opening polymerization oligomers |
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