Effect of the solvent polarity on the living ligated anionic polymerization of tert-butyl methacrylate and copolymerization with methyl methacrylate |
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Authors: | C. Zune C. Archambeau Ph. Dubois R. Jérôme |
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Affiliation: | Center for Education and Research on Macromolecules, University of Liège, Sart-Tilman, B6a, 4000 Liège, Belgium |
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Abstract: | An anionic polymerization of t-butyl methacrylate and a copolymerization with methyl methacrylate were initiated with an organolithium ligated with 10 equiv of LiCl. As a rule, the complexation of the active species by LiCl masked the effect that the polarity of the solvent might have on the molecular structure of the chains. © 2001 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 1774–1785, 2001 |
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Keywords: | anionic polymerization ligation solvation (meth)acrylates |
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