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Theoretical and experimental X-ray photoelectron spectroscopy investigation of ion-implanted nafion
Authors:Eufrozina A Hoffmann  Zoltan A Fekete  Ljiljana S Korugic-Karasz  Frank E Karasz  Eugene Wilusz
Institution:1. Department of Polymer Science and Engineering, University of Massachusetts, Amherst, Massachusetts 01003

Department of Physical Chemistry, University of Szeged, Szeged, Hungary H-6701;2. Department of Polymer Science and Engineering, University of Massachusetts, Amherst, Massachusetts 01003;3. U.S. Army Natick Soldier Center, Natick, Massachusetts 01760

Abstract:The membrane properties of a Nafion surface can be modified by ion implantation with N+ or F+. The results are presented of an X-ray photoelectron spectroscopy (XPS) study of implanted surfaces. For the interpretation of the XPS spectra, calculations using a semiempirical quantum chemical formalism (AM1) have been applied, in conjunction with a charge-potential model, to predict the C1s core electron binding energies. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 551–556, 2004
Keywords:semiempirical calculations  quantum chemistry  fluoropolymers  ESCA/XPS  theory
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