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Cucurbitacin and Triterpenoid Glycosides from Hemsleya giganthy
作者姓名:YaCHEN  MingHuaCHIU  KunGU  ZhongRongLI
作者单位:[1]DepartmentofChemistry,YunnanUniversity,Kunming650091 [2]LaboratoryofPhytochmistry,KunmingInstiuteofBotany,CAS,Kunming650204
基金项目:国家自然科学基金,云南省自然科学基金,members of analytical group in Phytochemistry Laboratory
摘    要:From rhizomes of Hemsleya giganthy collected in Shichuan of China,16 compounds were isolated.Among them,three compounds (8,9,15)are new natural products called Hemslecins G;Hemsgiganosides A and B;respectively.Their structures were elucidated as 7-hydroxy-23,24-dihydro-cucurbitacin F-25-O-acetate(8);3-O-(6‘‘‘‘‘‘‘‘-butyl ester-)-β-D-glu-curono-pyranosyl)-oleanolic acid-28-O-α-L-arabinopyranoside(9);3-O-β-D-glucuropyranosyl oleanolic acid-28-O-β-D-gluco pyranosyl-(1→6)-β-D-glucopyranoside(15)by spectroscopic and chemical means.

关 键 词:植物药  化学成分  结构鉴定  化学方法  分光镜  雪胆属植物  葫芦素  三萜类配糖体

Cucurbitacin and Triterpenoid Glycosides from Hemsleya giganthy
YaCHEN MingHuaCHIU KunGU ZhongRongLI.Cucurbitacin and Triterpenoid Glycosides from Hemsleya giganthy[J].Chinese Chemical Letters,2003,14(5):475-478.
Authors:Ya CHEN  Ming Hua CHIU  Kun GU  Zhong Rong Li
Abstract:From rhizomes of Hemsleya giganthy collected in Shichuan of China, 16 compounds were isolated. Among them, three compounds (8, 9, 15) are new natural products called Hemslecins G; Hemsgiganosides A and B; respectively. Their structures were elucidated as 7- hydroxy-23, 24-dihydro-cucurbitacin F-25-O-acetate (8); 3-O-(6-butyl ester-)-b-D-glu- curono- pyranosyl)-oleanolic acid-28-O-a-L-arabinopyranoside(9); 3-O-b-D-glucuropyranosyl oleanolic acid -28-O-b-D-gluco pyranosyl-(16)- b-D-glucopyranoside(15) by spectroscopic and chemical means.
Keywords:Hemsleya giganthy  Cucurbitaceae  Hemslecins G  Hemsgiganosides A  B    H
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