Electrical Conductance Studies in Aqueous Solutions of Glutaric Acid,Disodium Glutarate and Sodium Hydrogen Glutarate |
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Authors: | Alexander Apelblat Emanuel Manzurola Zoya Orekhova |
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Institution: | (1) Department of Chemical Engineering, Ben Gurion University of the Negev, Beer Sheva, 84105, Israel |
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Abstract: | Conductivity measurements of glutaric acid and disodium glutarate in dilute aqueous solutions were performed in the 288.15
to 323.15 K temperature range. The limiting equivalent conductances of glutarate anions, λ
o(HGlut−,T) and λ
o(1/2Glut2−,T), and the dissociation constants of glutaric acid, K
1(T) and K
2(T), were derived by the use of the Onsager and the Quint and Viallard conductivity equations. The applied molecular model was
successfully confirmed by analyzing the conductivities of sodium hydrogen glutarate at 298.15 K. |
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Keywords: | Aqueous solutions Glutaric acid Sodium hydrogen glutarate Disodium glutarate Limiting molar conductances Dissociation constants |
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