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Electrical Conductance Studies in Aqueous Solutions of Glutaric Acid,Disodium Glutarate and Sodium Hydrogen Glutarate
Authors:Alexander Apelblat  Emanuel Manzurola  Zoya Orekhova
Institution:(1) Department of Chemical Engineering, Ben Gurion University of the Negev, Beer Sheva, 84105, Israel
Abstract:Conductivity measurements of glutaric acid and disodium glutarate in dilute aqueous solutions were performed in the 288.15 to 323.15 K temperature range. The limiting equivalent conductances of glutarate anions, λ o(HGlut,T) and λ o(1/2Glut2−,T), and the dissociation constants of glutaric acid, K 1(T) and K 2(T), were derived by the use of the Onsager and the Quint and Viallard conductivity equations. The applied molecular model was successfully confirmed by analyzing the conductivities of sodium hydrogen glutarate at 298.15 K.
Keywords:Aqueous solutions  Glutaric acid  Sodium hydrogen glutarate  Disodium glutarate  Limiting molar conductances  Dissociation constants
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