| 五元瓜环与钕离子在四氯酸锌离子诱导下构筑的配合超分子自组装 |
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| 引用本文： | 丛航,陈凯,王传真,薛赛凤,张云黔,陶朱,祝黔江,张振琴.五元瓜环与钕离子在四氯酸锌离子诱导下构筑的配合超分子自组装[J].无机化学学报,2014,30(12):2839-2846. |
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| 作者姓名： | 丛航 陈凯 王传真 薛赛凤 张云黔 陶朱 祝黔江 张振琴 |
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| 作者单位： | 贵州省大环化学及超分子化学重点实验室, 贵州大学化学与化工学院, 贵阳 550025;贵州省大环化学及超分子化学重点实验室, 贵州大学化学与化工学院, 贵阳 550025;贵州省大环化学及超分子化学重点实验室, 贵州大学化学与化工学院, 贵阳 550025;贵州省大环化学及超分子化学重点实验室, 贵州大学化学与化工学院, 贵阳 550025;贵州省大环化学及超分子化学重点实验室, 贵州大学化学与化工学院, 贵阳 550025;贵州省大环化学及超分子化学重点实验室, 贵州大学化学与化工学院, 贵阳 550025;贵州省大环化学及超分子化学重点实验室, 贵州大学化学与化工学院, 贵阳 550025;南京医科大学药学院化学系, 南京 210029 |
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| 基金项目： | the support of National Natural Science Foundation of China (No.21101037 and 21272045);the Natural Science Foundation of the Department of Education of Guizhou Province |
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| 摘 要： | 在四氯酸锌离子诱导下,五元瓜环能与钕离子构筑形成二维配合超分子自组装。在HCl介质中,Zn2+容易形成四氯酸锌离子,在其诱导作用下,钕离子和五元瓜环端口羰基氧直接配位形成二维超分子自组装体。结果表明锌离子作为一种结构导向剂在形成瓜环基超分子自组装体中起到重要作用。
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| 关 键 词： | 超分子自组装 钕离子 五元瓜环 四氯锌酸根离子 |
| 收稿时间： | 2014/6/16 0:00:00 |
| 修稿时间： | 2014/9/17 0:00:00 |
Coordination and Supramolecular Assemblies of Neodymium Cation with Cucurbit[5]uril |
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| CONG Hang,CHEN Kai,WANG Chuan-Zeng,XUE Sai-Feng,ZHANG Yun-Qian,TAO Zhu,ZHU Qian-Jiang and ZHANG Zhen-Qin.Coordination and Supramolecular Assemblies of Neodymium Cation with Cucurbit[5]uril[J].Chinese Journal of Inorganic Chemistry,2014,30(12):2839-2846. |
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| Authors: | CONG Hang CHEN Kai WANG Chuan-Zeng XUE Sai-Feng ZHANG Yun-Qian TAO Zhu ZHU Qian-Jiang and ZHANG Zhen-Qin |
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| Institution: | Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China;Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China;Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China;Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China;Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China;Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China;Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China;School of Pharmacy, Nanjing Medical University, Nanjing 210029, China |
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| Abstract: | |
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| Keywords: | supramolecular assemblies neodymium (Nd3+ ) cation cucurbit[5]uril (Q[5]) tetrachlorozincate [ZnCl4]2- anion |
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