Organotin anions in solution and in the solid state |
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Authors: | T Birchall J Vetrone |
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Institution: | (1) Department of Chemistry, McMaster University, L8S 4M1 Hamilton, Ontario, Canada |
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Abstract: | Moessbauer data have been obtained for a series of organotin anions. The spectra of these anions in solution show the presence of two species, a singlet in the tin(IV) region and a doublet in the tin(II) region. The crystal structure of triphenyltin anion with potassium in 18-crown-6 as the cation has been determined. The Moessbauer spectrum of this sample is a doublet in the tin(II) region. |
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