Cyclopentadienylcobalt Complexes Containing Two Phosphine Ligands |
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| Authors: | Knizhnikov V A Shirokii V L Bazhanov A V Tychinskaya L Yu Maier N A |
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| Institution: | (1) Institute of Physical Organic Chemistry, Academy of Sciences Belarussian, Minsk, Belarus |
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| Abstract: | The ionic complexes C5H5Co(L)(Ph2PMe)I]+ I]- (L = Ph3P and Ph2PMe) were prepared by the reactions of cyclopentadienyl(triphenylphosphine)cobalt and cyclopentadienyl(methyldiphenylphosphine)cobalt diiodides with methyldiphenylphosphine. The treatment of these complexes with sodium tetraphenylborate results in the formation of C5H5Co(L)(Ph2PMe)I]+BPh4]- compounds. |
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