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Synthesis and Reactivity of a Neutral,Three‐Coordinate Platinum(II) Complex Featuring Terminal Amido Ligation |
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| Authors: | Colin M Kelly Doo‐Hyun Kwon Michael J Ferguson Steven M Bischof Orson L Sydora Daniel H Ess Mark Stradiotto Laura Turculet |
| Abstract: | A crystallographically characterized three‐coordinate, formally 14 electron PtII complex 1 featuring terminal amido ligation is reported. Computational analysis revealed relatively weak π donation from the amide lone pair to platinum and supports a 14‐electron assignment for 1 . Stoichiometric reactivity studies confirmed the viability of net O? H and C? H addition across, as well as isonitrile insertion into, the terminal platinum–amido linkage of 1 . |
| Keywords: | Amidoliganden Dichtefunktionalrechnungen Koordinationschemie Niederkoordinierte Komplexe Platin |