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Asymmetric Transfer Hydrogenation Catalyzed by Mesoporous MCM‐41‐Supported Chiral Ru‐Complex |
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| Authors: | Shaheen M Sarkar Mashitah Mohd Yusoff Md Lutfor Rahman |
| Abstract: | Chiral N‐sulfonyldiamine was successfully anchored on mesoporous MCM‐41 silica. The MCM‐41‐supported chiral N‐sulfonyldiamine was used as an efficient heterogeneous chiral ligand in the asymmetric transfer hydrogenation of ketones. This heterogeneous system offered satisfactory enantioselectivities up to 94 % with excellent conversions. |
| Keywords: | N‐sulfonyldiamine MCM‐41 Immobilization Asymmetric catalysis Transfer hydrogenation |