Functionalized enamines—XV: Reactivity patterns of carbene addition to morpholine enamine of 1-β-acetoxy-6-oxo-8a-methyl-Δ-octalin |
| |
Authors: | S.A.G. de Graaf U.K. Pandit |
| |
Affiliation: | S.A.G. de Graaf,U.K. Pandit*, |
| |
Abstract: | Carbenes3a-e add to the α-side of the first double bond of dienamine2 (title compound) to give 1 : 1 adducts4a-e, Chlorofluorocarbene3e gives, in addition, ketone7, corresponding to β-addition at the second double bond of2, and a 2 : 1 adduct8. The reaction of2 with dichlorocarbene3a yields, besides4a, novel ring-expansion products5 and6 corresponding to addition of two moles of3a. Ethoxycarbonylcarbene3f reacts with the dienamine (2) to give isomeric esters9 and10a,b. The structure assignments and the mechanism of formation of the reaction products are discussed. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|