| 芳香胺及其氮氧化物合希土配合物的研究 V.2, 2'—联喹啉—N, N'—二氧化物合硝酸希土固体配合物的合成及其性质 |
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| 引用本文： | 袁景利,课民裕,甘新民.芳香胺及其氮氧化物合希土配合物的研究 V.2, 2''—联喹啉—N, N''—二氧化物合硝酸希土固体配合物的合成及其性质[J].无机化学学报,1987,3(4):20-27. |
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| 作者姓名： | 袁景利 课民裕 甘新民 |
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| 作者单位： | 兰州大学化学系
(袁景利，课民裕)，兰州大学化学系(甘新民) |
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| 摘 要： | 在无水乙醇和氯仿混合溶剂中使重希土硝酸盐与2,2′—联喹啉—N,N′—二氧化物(BiqO_2)作用,制得了固体配合物Ln(BiqO_2)(NO_3)_3·2H_2O(Ln=Tm,Yb,Lu,Y)。通过元素分析、X光粉末衍射物相分析、差热—热重分析、红外光谱、紫外光谱、溶解性及摩尔电导测定,研究了配合物的组成及其有关性质。
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| 关 键 词： | 硝酸铥 镱 镥和钇2-2′—联喹啉—N N′—二氧化物 希土配合物 |
| 收稿时间： | 1986/5/14 0:00:00 |
STUDIES ON RARE EARTH COMPLEXES WITH HETEROCYCLIC AROMATIC AMINE AND THEIR N-OXIDE V. SYNTHESIS AND "CHARACTERlZATlON OF SOLID COMPLEXES OF RARE EARTH NITRATES WITH 2, 2'-BIQUINOLINE-N, N'-DIOXIDE |
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| Yuan Jingli,Tan Minyu and Gan Xinmin.STUDIES ON RARE EARTH COMPLEXES WITH HETEROCYCLIC AROMATIC AMINE AND THEIR N-OXIDE V. SYNTHESIS AND "CHARACTERlZATlON OF SOLID COMPLEXES OF RARE EARTH NITRATES WITH 2, 2''-BIQUINOLINE-N, N''-DIOXIDE[J].Chinese Journal of Inorganic Chemistry,1987,3(4):20-27. |
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| Authors: | Yuan Jingli Tan Minyu and Gan Xinmin |
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| Affiliation: | Department of Chemistry, Lanzhou University,Department of Chemistry, Lanzhou University and Department of Chemistry, Lanzhou University |
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| Abstract: | The new solid complexes Ln(BiqO2)(NO3)3·2H2O(Ln-Tm, Yb, Lu, Y and BiqO2=2, 2'-biquinoline-N, N'-dioxide)have been synthesized using nonaqueous ethanol and chloroform as reaction medium. These complexes have been characterized by elemental analyses, X-ray powder diffraction, differential thermal analyses(DTA), thermogravimetry(TG), infrared spectra, ultraviolet spectra and molar conductances. |
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| Keywords: | thulium ytterbium lutetium and yttrium nitrates 2 2'bi-quinoline-N N'-dioxide lanthanide complexes |
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