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Direct Esterification of Aromatic Aldehydes with Tetraphenylphosphonium Bromide under Oxidative N‐Heterocyclic Carbene Catalysis
Authors:Bandaru T. Ramanjaneyulu  Manish Pareek  Virsinha Reddy  R. Vijaya Anand
Affiliation:Department of Chemical Sciences, Indian Institute of Science Education and Research (IISER) Mohali, Sector 81, Knowledge City, S.?A.?S. Nagar, Mohali, Punjab?–?140306, India, (fax: +91‐172‐2240266)
Abstract:An unconventional reagent, tetraphenylphosphonium bromide, was employed as a phenyl source in the direct transformation of aromatic aldehydes to the corresponding phenyl esters under oxidative N‐heterocyclic carbene (NHC) catalysis. The phenyl esters were obtained in moderate yields under mild and organocatalytic conditions.
Keywords:Organocatalysis  Catalysis  Carbenes  Aerobic oxidation  Esterification  Tetraphenylphosphonium bromide
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