Regularity of Intermittent Bursts in BriggsRauscher Oscillating Systems with Phenol |
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| Authors: | Željko D. Čupić Ljiljana Z. Kolar‐Anić Slobodan R. Anić Stevan R. Maćešić Jelena P. Maksimović Marko S. Pavlović Maja C. Milenković Itana Nuša M. Bubanja Emanuela Greco Stanley D. Furrow Rinaldo Cervellati |
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| Affiliation: | 1. Institute of Chemistry, Technology and Metallurgy, University of Belgrade, Center of Catalysis and Chemical Engineering, Njego?eva 12, RS‐11000 Belgrade, (phone: +381‐11‐2630213;2. fax +381‐11‐2637977);3. Faculty of Physical Chemistry, University of Belgrade, Studentski trg 12?–?16, RS‐11000 Belgrade;4. Dipartimento di Chimica ‘G. Ciamician', Università di Bologna, Via Selmi 2, IT‐40126 Bologna;5. Emeritus, Berks College, Pennsylvania State University, Reading, PA 19610, USA |
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| Abstract: | The intermittency or intermittent bursting as the type of dynamic state when two qualitatively different behaviors replace one another randomly during the course of the reaction, although all the control parameters remain constant, is found in the Briggs? Rauscher oscillating system moderated by a very small amount of phenol. Within a range of phenol concentrations, the oscillation amplitude is diminished considerably, and after oscillations cease, they repeat intermittently, giving several bursts of oscillations. For the concentrations used here, the range of phenol concentrations where intermittent bursting oscillations occur in a closed reactor is ca. 1.8×10?5 to 3.6×10?5 M . Bursting also occurs in an open reactor and can be sustained indefinitely at 5.53×10?5 M concentration. The intermittent bursting behavior is robust, and can be achieved at a variety of conditions. |
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| Keywords: | Briggs Rauscher Oscillating reactions Intermittent bursting Phenol |
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