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P123 / SDS水溶液中碳酸钙结晶及形貌的研究
引用本文:郭静,曹洁明,郑明波,邓少高,蒋锡华,王海燕,陶杰.P123 / SDS水溶液中碳酸钙结晶及形貌的研究[J].无机化学学报,2007,23(4):725-728.
作者姓名:郭静  曹洁明  郑明波  邓少高  蒋锡华  王海燕  陶杰
作者单位:南京航空航天大学材料科学与技术学院,纳米材料研究所,南京,210016
基金项目:国家自然科学基金;江苏省自然科学基金
摘    要:仿生合成是模拟生物矿化合成人工晶体的一种方法。在生物矿化中的无机矿物往住是在有机基质的参与下形成的,它们在有机基质上成核,并且在整个结晶过程中受到有机基质及其他生命活动的调控,因而在晶体的形态、尺寸、以及取向上都具有高度的统一性和有序性1],

关 键 词:碳酸钙    形貌    胶束    晶体生长
文章编号:1001-4861(2007)04-0725-04
修稿时间:2006-11-06

Synthesis of CaCO3 with Different Morphologies in Presence of P123/SDS Solution
GUO Jing,CAO Jie-Ming,ZHENG Ming-Bo,DENG Shao-Gao,JIANG Xi-Hu,WANG Hai-Yan and TAO Jie.Synthesis of CaCO3 with Different Morphologies in Presence of P123/SDS Solution[J].Chinese Journal of Inorganic Chemistry,2007,23(4):725-728.
Authors:GUO Jing  CAO Jie-Ming  ZHENG Ming-Bo  DENG Shao-Gao  JIANG Xi-Hu  WANG Hai-Yan and TAO Jie
Institution:Nanomaterials Research Institute, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016,Nanomaterials Research Institute, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016,Nanomaterials Research Institute, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016,Nanomaterials Research Institute, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016,Nanomaterials Research Institute, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016,Nanomaterials Research Institute, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 and Nanomaterials Research Institute, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016
Abstract:Different morphologies of CaCO3 have been synthesized through controlling the molar ratios of the P123 and SDS in the mixture solution. The morphologies and structures of samples have been characterized using SEM and XRD. SEM images show diverse morphologies of CaCO3 at different SDS concentrations due to the different micelle formation. Mechanisms of the different micelle formation are proposed for the formation of the different structure.
Keywords:CaCO3  morphologies  micelle  crystal growth
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