Reaction of fullerene C60 with 2-azido-4,6-diphenylpyrimidine |
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| Authors: | Romanova,I. P.,Yusupova,G. G.,Yakhvarov,D. G.,Larionova,O. A.,Mochul" skaya,N. N.,Sidorova,L. P.,Charushin,V. N.,Zverev,V. V.,Sinyashin,O. G. |
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| Affiliation: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088 Kazan, Russian Federation;(2) Ural State Industrial University, 19 ul. Mira, 620002 Ekaterinburg, Russian Federation;(3) Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 20 ul. S. Kovalevskoi, 620219 Ekaterinburg, Russian Federation |
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| Abstract: | The first representative of the pyrimidine-substituted [60]fullereno[1,2-b]aziridines was synthesized by the reaction of fullerene C60 with 2-azido-4,6-diphenylpyrimidine. 2-(Azahomo[60]fullereno)-4,6-diphenylpyrimidine was found to be formed as a by-product. The electrochemical properties of the adducts were studied. |
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| Keywords: | [60]fullerene 2-azidopyrimidines [60]fullereno[1,2-b]aziridine azahomo[60]fullerene electrochemistry |
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