| Crystal Structure of Chiral Acetato-bridged Binuclear Cyclopalladated Complex [Pd(μ-O_2CMe)(S-C_6H_4CHMeNH_2)]_2 |
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| 引用本文： | 杨帆,李一平,聂娟,汤杰,何鸣元.Crystal Structure of Chiral Acetato-bridged Binuclear Cyclopalladated Complex [Pd(μ-O_2CMe)(S-C_6H_4CHMeNH_2)]_2[J].中国化学,2003(8). |
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| 作者姓名： | 杨帆 李一平 聂娟 汤杰 何鸣元 |
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| 作者单位： | Center for the Chemistry of Ionic Liquids，Department of Chemistry，East China Normal University，Center for the Chemistry of Ionic Liquids，Department of Chemistry，East China Normal University，Center for the Chemistry of Ionic Liquids，Department of Chemistry，East China Normal University，Center for the Chemistry of Ionic Liquids，Department of Chemistry，East China Normal University，Center for the Chemistry of Ionic Liquids，Department of Chemistry，East China Normal University Shanghai 200062，China，Shanghai 200062，China，Shanghai 200062，China，Shanghai 200062，China，Shanghai 200062，China |
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| 基金项目： | theNationalNaturalScienceFoundationofChina (No .2 0 172 0 16)，ShanghaiPhosphorProjectofScience&Tech nologyforExcellentYoungResearch (No .0 1QA14 0 17)，theScienceandTechnologyDevelopmentFoundationofShanghai (No .0 1JC14 0 0 2 ) |
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| 摘 要： | IntroductionSinceKleiman ,Copeandcoworkersdescribedthefirstexampleofcyclopalladatedcomplex ,1,2 ithasarousedchemists’greatinterestsinthestructuresandproperties .Manycrystalstructuresofmonomericcyclopalladatedcom plexeshavebeeninvestigated .3,4 However ,structuresofacetato bridgedbinuclearcyclopalladatedcomplexesarerarelyreported .5Inthispaper,weobtainedthesinglecrystalofchiralacetato bridgedbinuclearcyclopalladatedcomplex Pd (μ (O2 CMe) (S C6 H4 CHMeNH2 ) ]2 (1)whichwasdeterminedbyasi…
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| 关 键 词： | chiral cyclopalladated complex crystal structure α methylbenzylamine |
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